审稿人看走眼也属正常 案例来源:CCDC[1] 2236602. Phytochemistry 2025, 231, 114344. DOI[2]:10.1016/j.phytochem.2024.114344. 审稿意见如下 审稿意见 | | There is a serious error in the crystal structure for 2; the hydrogen atom on C14C is missing. This atom (H14C) should be added and the structure refined again. Remember to update the deposited CIF at the CCDC. The _chemical_formula_moiety value in the CIF currently is '3(C24 H26 O8), C24 H25 O8, 4(H2 O)'. When corrected, it should be '4(C24 H26 O8), 5(H2 O)'. Note that there are five water molecules in the structure (containing O1D, O2D, O3D, O4D & O5D), not four! | 2的晶体结构中存在严重错误,C14C上的氢原子缺失。需添加氢原子(H14C)并重新精修结构。请记得更新存储在CCDC中的CIF。当前,CIF中_chemical_formula_moiety的值为'3(C24 H26 O8), C24 H25 O8, 4(H2 O)'。修正后,它应为'4(C24 H26 O8), 5(H2 O)'。请注意,该结构中有5个水分子(包含O1D、O2D、O3D、O4D和O5D),而不是4个! |
审稿人在审稿意见中着重强调,结构中的水分子是5个,而不是4个,这着实给作者带来了困惑,当时笔者看了该数据,如图1所示,单从晶体数据来看,不可能是5个水分子。 ▲图1 部分讨论过程 后来审稿人应该是意识到自己搞错了,于是通过编辑发了如下信息: Reviewer 2 has sent the following message - Could you please check and make the necessary changes in your article. | 审稿人2已发送以下信息——请检查您的文章并进行必要的更改。 | “in my review I wrote that there are five water molecules in the crystal structure of compound 2. There actually a total of four, since two (O1D & O2D) are disordered and their occupancies sum to 1. You can alert the authors to my mistake.” | “在我的评论中,我写道化合物2的晶体结构中有5个水分子。实际上总共有四个,因为两个(O1D和O2D)是无序的,它们的占有率之和为1。你可以提醒作者注意我的错误。” |
这种情况属于是审稿人看走眼,提了错误的审稿意见,不过审稿人及时发现并给出提醒,虽然好一顿折腾,倒也不是什么大问题。 如果审稿人没有发现自己的错误,也没有给出提醒,其实作为投稿人,只要有数据支撑,是可以提出反驳的,比如提供热重数据,元素分析等其他辅助表征数据来支持自己的观点,不要盲目认为审稿人说的就一定是正确的。 相关视频: 审稿人看走眼也属正常:https://www.bilibili.com/video/BV1PMcFeaEAQ 参考文献 [1] (a) Allen, F. H.The Cambridge Structural Database: A Quarter of a Million Crystal Structuresand Rising. Acta Cryst. 2002, B58, 380–388. DOI:10.1107/S0108768102003890. (b) Groom, C. R.; Bruno, I. J.; Lightfoot, M.P.; Ward, S. C. The Cambridge Structural Database. Acta Cryst. 2016, B72, 171–179. DOI:10.1107/S2052520616003954. (c) Mitchell, J.; Robertson, J. H.; Raithby,P. R. Cambridge Crystallographic Data Centre (CCDC). Comprehensive Coordination Chemistry III 2021, 413–437. DOI: 10.1016/B978-0-12-409547-2.14829-2. [2] (a) InternationalOrganization for Standardization (2012). ISO 26324:2012. Information and Documentation – Digital Object Identifier System. http://www.iso.org/iso/catalogue_detail.htm?csnumber=43506. (b) McDonald J. D.;Levine-Clark, M. Encyclopedia of Libraryand Information Sciences. Fourth Edition, CRC Press, 2017. DOI: 10.1081/e-elis4. (c) Liu, J. Digital ObjectIdentifier (DOI) and DOI Services: An Overview. Libri 2021, 71, 349‒360. DOI:10.1515/libri-2020-0018. (d) International Organization forStandardization (2022). ISO 26324:2022. Informationand Documentation – Digital Object Identifier System. https://www.iso.org/standard/81599.html 声明:本文仅代表个人观点,笔者学识有限,资料整理过程中可能存在疏漏错误,请不吝指正。 如需PDF文档,请从以下链接下载: 通过网盘分享的文件:审稿人看走眼也属正常.pdf
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